Net user USERNAME /domain
Using Powershell
get-aduser -filter * -properties passwordlastset, passwordneverexpires |ft Name, passwordlastset, Passwordneverexpires
To display the expiration date rather than the password last set date, use this command.
Get-ADUser -filter {Enabled -eq $True -and PasswordNeverExpires -eq $False} –Properties "DisplayName", "msDS-UserPasswordExpiryTimeComputed" | Select-Object -Property "Displayname",@{Name="ExpiryDate";Expression={[datetime]::FromFileTime($_."msDS-UserPasswordExpiryTimeComputed")}}